CNR ExploRA

Articolo in rivista, 2022, ENG, 10.3390/ma15134612

Fluorinated Agents Effects on Orthodontic Alloys: A Descriptive In Vitro Study

Condo R.; Carli E.; Cioffi A.; Cataldi M.E.; Quinzi V.; Casaglia A.; Giancotti A.; Pirelli P.; Lucarini I.; Maita F.; Maiolo L.; Mampieri G.

Department of Clinical Sciences and Translational Medicine, University of Rome "Tor Vergata", Via Montpellier 1, Rome, 00133, Department of Clinical Sciences and Translational Medicine, University of Rome "Tor Vergata", Via Montpellier 1, 00133, Rome, Italy, , Italy; Department of Surgical Medical and Molecular Pathology and Critical Care Medicine, University of Pisa, Pisa, 56126, Department of Surgical Medical and Molecular Pathology and Critical Care Medicine, University of Pisa, 56126, Pisa, Italy;, , Italy; Department of Life, Health & Environmental Sciences, Postgraduate School of Orthodontics, University of L'Aquila, L'Aquila, 67100, Department of Life, Health & Environmental Sciences, Postgraduate School of Orthodontics, University of L'Aquila, 67100, L'Aquila, Italy;, , Italy; Institute for Microelectronics and Microsystems--Unit of Rome, National Research Council, Via del Fosso del Cavaliere 100, Rome, 00133, Institute for Microelectronics and Microsystems--Unit of Rome, National Research Council, Via del Fosso del Cavaliere 100, 00133, Rome, Italy, , Italy

Fluoride-based mouthwashes and gels are preventive measures in countering demineralization and caries but, modifying environmental acidity, can reduce the wet corrosion resistance of orthodontic alloys. To evaluate chemical stability, in vitro experiments were conducted on stainless steel and nickel-titanium wires, weighed before and after immersion in household fluorinated mouthwashes and gels, measuring weight variations and elution of metal ions from acid corrosion phenomena. Elution samples were analyzed by inductively coupled plasma mass spectrometry, detecting residual ion concentration, while surface changes were analyzed under scanning electron microscopy. Results showed stainless steel wires do not undergo significant erosion when exposed to most fluorinated mouthwashes but, at prolonged exposure, alloys elute gradually greater amounts of metals and Ni-Ti wires become more sensitive to some mouthwashes. Ions' elution varies considerably, especially for Ni-Ti wires, if exposed to household fluorinated gels, for which significant negative values were obtained. Changes, affecting wires' outer layer, negatively act on shiny appearance and luster, reducing corrosion resistance. Although examined orthodontic wires showed good chemical stability and low toxicity, surface corrosion from exposure to fluorinated agents was observed. Home use must be accompanied by clinician prescription and, for household dental gels, must follow manufacturers' recommendations, ensuring prophylactic action without damaging alloys surfaces.

Materials (Basel) 15