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Articolo in rivista, 2024, ENG, 10.1016/j.chemgeo.2023.121840

Deep segregation and crystallization of ultra-depleted melts in the sub-ridge mantle

Ferrando, C; Borghini, G; Sani, C; Genske, F; Ligi, M; Stracke, A; Sanfilippo, A;

1 Univ Pavia, Dept Earth & Environm Sci, I-27100 Pavia, Italy 2 Univ Genoa, Dept Earth Environm & Life Sci, I-16132 Genoa, Italy 3 Univ Milan, Dept Earth Sci Ardito Desio, I-20133 Milan, Italy 4 Univ Munster, Inst Mineral, Munster, Germany 5 Natl Res Council CNR, ISMAR, Bologna, Italy 6 Natl Res Council CNR, IGG, Pavia, Italy 7 Univ Genoa, Dipartimento Sci Terra Ambiente & Vita, Corso Europa 26, I-16132 Genoa, Italy

Partial melting of mantle peridotite from which considerable amounts of melt have been extracted during prior melting episodes generates melts characterized by low incompatible element contents and very low ratios of highly to moderately incompatible elements, so-called 'ultra-depleted' melts. Reaction of peridotite with percolating ultra-depleted melts has been inferred from petrological-geochemical studies of abyssal peridotites and ophiolites. But so far, direct evidence for the existence of ultra-depleted melts, only comes from rare melt inclusions. Here, we show that a pyroxenite layer within abyssal peridotite from the Mid Atlantic Ridge (8 degrees N, Doldrums Fracture Zone) formed by crystallization of a segregated melt that is highly depleted in incompatible elements, at >27 km-depth beneath the ridge axis (at T similar to 1250 degrees C), and with little or no modification by interaction with the host harzburgite. During exhumation, the pyroxenite experienced decompression and partial re-equilibration under plagioclase-facies conditions (similar to 1060 degrees C and similar to 15 km depth). The high Hf isotope ratio (epsilon Hf = 40.3) of the pyroxenite clinopyroxene is inherited from a melt sourced from an ultra-depleted peridotite that evolved with high Lu/Hf. The associated MORB-like Nd isotope ratios (epsilon Nd = 10.6), however, imply a long-term evolution of the source peridotite with composition moderately depleted in incompatible elements (rather low Sm/Nd). These compositions are different from the host harzburgite, but typical for peridotites that have melted and partially reacted with migrating melts in ancient times. Hence, the pyroxenite investigated here is a partial melt from an ultra-depleted peridotite that has become re-enriched in incompatible elements and clinopyroxene. This melt crystallized in the oceanic lithosphere, and partially re-equilibrated at low pressure during exhumation. Overall, our results show that renewed melting of ultra-depleted peridotites with a complex history of prior melting and melt-rock reaction occurs, and that such melts migrate through the sub-ridge mantle, and can thus contribute to mid ocean ridge magmatism, although to a still unknown extent.

Chemical geology 644