Articolo in rivista, 2006, ENG
C. Carlini, S. Giaiacopi, F. Marchetti, C. Pinzino, A. M. Raspolli Galletti, and G. Sbrana
Dipartimento di Chimica e Chimica Industriale, UniVersity of Pisa, Via Risorgimento 35,56126 Pisa, Italy, and Istituto per i Processi Chimico-Fisici (IPCF)-CNR, Area delle Ricerca del CNR, Via G. Moruzzi 1, 56124 Pisa, Italy
The polymerization of norbornene in the presence of different bis(salicylaldiminate)copper(II) complexes and methylalumoxane has been investigated. In all cases a high molecular weight vinyl-type polymer was obtained. The presence of electron-withdrawing nitro groups on the chelate ligand markedly increased the activity of the catalyst. The influence on the catalytic performances and polymer characteristics as a function of reaction parameters, such as temperature, duration, and content of free trimethyl aluminum in the commercial MAO, was studied.
Organometallics 25 , pp. 3692–3697
ID: 39357
Year: 2006
Type: Articolo in rivista
Creation: 2009-06-16 00:00:00.000
Last update: 2012-06-04 10:49:38.000
CNR authors
CNR institutes
External IDs
CNR OAI-PMH: oai:it.cnr:prodotti:39357
ISI Web of Science (WOS): 000238848600023